It is a colourless, transparent liquid which has an unpleasant odour. Methyl acrylate is formed in good yield on pyrolysis of methyl lactate in the presence of ethenone ketene. Method s38 for methyl acrylate was issued on 12674, and evaluated over a range of. Keep unnecessary and unprotected personnel from entering. Identification product identifier used on the label methyl acrylate recommended use of the chemical and restriction on use recommended use. Vadhavkar, hereby grant permission to the wallace memorial library of the rochester institute of technology to reproduce this document in whole or in part that any reproduction will not be for commercial use or profit.
A method for producing amphocarboxylpropionate comprising initiating the reaction of methyl acrylate with 2alkyl imidazoline in the substantial absence of water. It is useful in the preparation of polymers having rigid, flexible, ionic, nonionic, hydrophobic, or hydrophilic properties. Methyl acrylate shall be tested for purity, water content, color, acidity, and methyl ether of hydroquinone content, and shall conform to the requirements of the specification. Less frequently, it is a precursor in synthesis via transesterification. Methyl acrylate 1459 wikisource, the free online library.
Keep patient calm, remove to fresh air, seek medical attention. Methyl acrylate, stabilized is a colorless volatile liquid with an acrid odor. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Methyl acrylate stabilised with hydroquinone monomethyl ether for synthesis.
Flush with copious amounts of water for at least 15 minutes. H412 harmful to aquatic life with long lasting effects. Methyl acrylate is a contact allergen present in nail lacquer methyl acrylate is a volatile alpha beta unsubstituted methyl ester used in the preparation of polyamidoamine pamam dendrimers typically by michael addition with a primary amine. Polymerization of methyl acrylate and as comonomer with ethylene using singlesite catalysts by sameer s. Methyl acrylate is an organic compound, more accurately the methyl ester of acrylic acid. Butyl acrylatemethyl methacrylate polymers cas 25852373. Pma, though softer than polymethyl methacrylate pmma, is tough, leathery, and flexible it has a low glasstransition temperature about 10c 12. Sds of methyl acrylate, safety data sheets, cas 96333. Methyl acrylate is used in the production of coatings, elastomers, adhesives, thickeners, surfactants, fibers, plastics, textiles and inks. Precautionary statements prevention p210 keep away from heatsparksopen flameshot surfaces. India veritas house, 70 mint road, fort, mumbai 400 001. High yields are also observed in 1,4additions to ethyl acrylate or acrylonitrile. A material safety data sheet has been compiled for methyl acrylate that contains.
Methyl acrylate methyl acrylate acrylic acid, methyl ester, methyl 2propenoate ch2chcoch3 ii o general description methyl acrylate is a clear, colorless, volatile liquid with a slight solubility in water and complete solubility in alcohols, ethers and many organic solvents. Wear appr opriate personal protective equipment as specified in section 8. It is also a reagent in the synthesis of various pharmaceutical intermediates. Methyl acrylate 2552 wikisource, the free online library. Cdc niosh pocket guide to chemical hazards methyl acrylate. Astm d4709 072012 standard specification for methyl acrylate. Identification product identifier used on the label methyl acrylate recommended use of the chemical and restriction on. Acrylonitrile copolymer with 6% methyl acrylate in presence of sodium 2 methyl 2 propene 1 sulfonate is a white powder with average particle size of. Sds 2isobutyl2 methyl 1,3dioxolan4yl methyl acrylate. Methyl methacrylate revision date 26jan2018 lower 2. Polymerization of methyl acrylate and as comonomer with. Material safety data sheet methyl acrylate lg chem.
Highly toxic by inhalation, ingestion and skin absorption. Chcooch find msds or sds, a coa, data sheets and more information. Methyl acrylate is a highly flammable product, and the appropriate precautions must be t aken in handling it. Please ensure that this msds is given to, and explained to people using this product. The substance identity section is calculated from substance identification information from all echa databases. Ethyl acrylate is an organic compound with the formula ch 2 chco 2 ch 2 ch 3. Methyl acrylate shall be stored in amber bottles or protect from light by other means to aid in preventing polymerization.
Polyacrylonitrile copolymer with 6% methacrylic acid. Show this safety data sheet to the doctor in attendance. Accidental release measures ventilate area of leak or spill. It is mainly produced to make acrylate fiber, which is used to weave synthetic carpets. The precision, as determined from the pooled relative standard deviation s r, was determined to be 0. Methyl acrylate shall be stored in amber bottles or protect from light. The benzyl ring disperses pigments or other aromatic molecules for ink applications. The effects of temperature, the initial molar ratio of n butanol to acrylic acid, catalyst loading, and the ratio of membrane area to reaction volume s v were studied. December 23, 2014 the dow chemical company page 3 of 6 fire or explosion. Heck reaction of iodobenzene with methyl acrylate in the presence of triethylamine. Fire and explosion data flammability of the product. Material safety data sheet msds styrene stabilized cas no. Another patent describes the dehydration of methyl lactate over zeolites.
Second, we incorporate additional comonomer, namely, hydroxyethyl acrylate, methyl methacrylate and acrylic acid, and study its in. Vapors may irritate the eyes and respiratory system. Section 1 chemical product and company identification. Methyl acrylate also known as acrylic acid methyl ester, and methyl 2propenoate is an ester of acrylic acid and has the formula c 4 h 6 o 2. Structure, properties, spectra, suppliers and links for. A series of monomeric acrylatemethacrylate esters methyl acrylate, ethyl acrylate, methyl methacrylate, and ethyl methacrylate as well as acrylic acid were examined for genotoxic activity in l5178y mouse lymphoma cells without exogenous activation. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Search results for methyl acrylate at sigmaaldrich. Absorb with noncombustible material such as dirt or sand. The pervap 2201 membrane showed high selectivity to water in the nbutanol, acrylic acid, nbutyl acrylate, and water reaction system.
The effects of temperature, the initial molar ratio of n butanol to acrylic acid, catalyst loading, and the ratio of. It is mainly produced for paints, textiles, and nonwoven fibers. Lc 50 values for rats acutely exposed to vapors of acrylic and methacrylic acid esters. Acrylic ester, for manufacturing polymers and for use as a feedstock.
Ground and bond all containers and handling equipment. Methyl acrylate is a colorless volatile liquid with an acrid odor. Polyethyleneco methyl acrylate coglycidyl methacrylate 1 product result match criteria. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the molecular and structural formulas. Nmorpholinoacetonitrile gives good yields of 1,4adducts with methyl crotonate, methyl methacrylate, diethyl maleate and ethyl propiolate under catalysis of sodium methoxide in thf. Methylacrylate is a colorless liquid above its freezing point of 75c 103f. Methyl acrylate supplier chemical solutions solventis. A series of monomeric acrylate methacrylate esters methyl acrylate, ethyl acrylate, methyl methacrylate, and ethyl methacrylate as well as acrylic acid were examined for genotoxic activity in l5178y mouse lymphoma cells without exogenous activation. Methyl acrylate can be prepared by debromination of methyl 2,3dibromopropanoate with zinc.
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